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Dioxolanes

Dioxolane is a heterocyclic acetal with the formula (CH2)2O2CH2. It is related to tetrahydrofuran by exchanging an oxygen for the CH2 group. The isomer 1,2-dioxolane (in which the two oxygen centers are adjacent) is a peroxide. 1,3-Dioxolane is used as solvent and comonomer in polyacetal. The dioxolane-type and their hydrogenolysis can provide very valuable partially protected building blocks either for oligosaccharide syntheses or sugar transformations.

2-((4-fluorophenoxy)methyl)-1,3-dioxolane

((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene) bis(4-methylbenzenesulfonate)

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

ethyl (S,E)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylacrylate

methyl (4R,5S)-2,2,5-trimethyl-1,3-dioxolane-4-carboxylate

3-(1,3-Dioxolan-2-yl)aniline

N-(1,3-Dioxolan-2-ylmethoxy)benzenecarboximidoyl cyanide

2-(1-Bromoethyl)-2-ethyl-1,3-dioxolane

1-Bromo-4-(1,3-dioxolan-2-yl)-3-fluorobenzene

2-(1,3-dioxolan-2-yl)aniline

2-(Bromomethyl)-2-phenyl-1,3-dioxolane

2-(2-Nitrophenyl)-1,3-dioxolane

2-(2-bromophenyl)-2-methyl-1,3-dioxolane

(3aR,4R,6R,6aR)-2,2-Dimethyl-6-((trityloxy)methyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-ol

1-Bromo-2,4-dimethoxy-5-(1,3-dioxolan-2-yl)benzene

(1,3-dioxolan-2-yl)methanol

2,2-dimethyl-1,3-dioxolane-4-carboxylic acid

Potassium (2-(1,3-dioxolan-2-yl)ethyl)trifluoroborate

1-(1,3-dioxolan-2-yl)propan-2-one

2-(4-Bromo-2,6-difluorophenyl)-1,3-dioxolane

2-(3,5-bis(benzyloxy)phenyl)-1,3-dioxolane

(R)-4-Iodomethyl-2,2-dimethyl-[1,3]dioxolane

2-(2-methyl-1,3-dioxolan-2-yl)propanal

2-(2-ethyl-1,3-dioxolan-2-yl)acetaldehyde